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61.
In this study, chemically bonded phosphate ceramic coatings (CBPCCs) with different contents of aluminum phosphate (AP) are prepared on stainless steel (AISI 304L). Differential scanning calorimetry, X-ray diffraction, contact angle test, and a tribocorrosion experiment are carried out to clarify the role of AP in the tribocorrosion performance of CBPCCs. The results show that, with the increase in the AP content, the enthalpy of curing increases because of the greater formation of the bonding phase AlPO4. Both in static corrosion and in tribocorrosion, the corrosion current density of CBPCCs achieves the lowest value when the weight ratio of AP to polytetrafluoroethylene is about 0.78. Additionally, the influence mechanism of AP on tribocorrosion is clarified. AlPO4 from the reaction between AP and Al2O3 has excellent mechanical properties and can enhance the wear resistance of CBPCCs by reducing the mechanical wear and the increased wear due to corrosion. The alumina particles wrapped by AlPO4 can form a dense and smooth surface and change the direction of electrolyte propagation, which leads to the increase in the tribocorrosion resistance of CBPCCs. 相似文献
62.
针对路面渗水仪底座和路面的密封性能不良问题,运用TRIZ创新方法的因果链、技术矛盾、物理矛盾、进化分析等工具找到原因,获得解决方案。通过调研及试用,不断优化及调整所选方案,达到最优解决效果。应用效果证明TRIZ理论有助于创新并快速解决工程实际问题。 相似文献
63.
Hiromi Eba Yuki Masuzoe Toru Sugihara Hayao Yagi Tian Liu 《International Journal of Hydrogen Energy》2021,46(18):10642-10652
Ammonia generation was studied in the reaction between water and nitrogen-containing iron at 323 K and atmospheric pressure. Similar to metallic Fe, the interstitial compound Fe3N reduced water through Fe oxidation to produce hydrogen gas, while the N combined with atomic hydrogen to produce ammonia as a byproduct. The addition of carbon dioxide to this system accelerated the reaction with concomitant consumption of carbon dioxide. The promoted ammonia production upon addition of carbon dioxide can be attributed to the generation of atomic hydrogen from the redox reaction of carbonic acid and Fe, as well as removal of used Fe from the reaction system through the formation of a soluble carbonato complex. When carbonate was added to the reaction system, the production rates of ammonia and hydrogen increased further. The results here confirmed that ammonia can be synthesized from iron nitride under mild conditions by utilizing carbon dioxide. 相似文献
64.
65.
A.A. Khalili Tabas B. Beidokhti A.R. Kiani-Rashid 《International Journal of Hydrogen Energy》2021,46(1):1012-1022
Different heat treatment cycles were designed in order to investigate the effect of microstructural changes on hydrogen induced cracking resistance (HIC) and mechanical properties of the electric resistance welded steel. The heat treating of the as-welded specimen improved the ductility and impact toughness. After heat treatment, the uniform hardness profile was obtained for the welded specimens. The removal of local hard zones reduced the risk of HIC. The chemical composition and clustering of inclusions have a deleterious effect on cracking resistance in the H2S environment. Aluminosilicate compounds and MnS inclusions were favorite sites for HIC. The most promising post weld heat treatment for improving mechanical properties and the resistance to HIC was the application of two-cycle quenching followed by tempering. 相似文献
66.
《International Journal of Hydrogen Energy》2021,46(70):34970-34982
Alloy hardened steels offer excellent combination of mechanical properties, hardenability and corrosion resistance. 34CrMo4 is a medium carbon, low alloy steel widely used due to a good combination of high-strength, toughness and wear resistance. However, this steel experiences hydrogen embrittlement (HE), a complex phenomenon depending on the composition and microstructure. This work estimates de loss of the mechanical properties caused by hydrogen in electrochemically H-charged specimens in absence of mechanical stress but also, at low strain rate and constant load. H-charging for 2 and 6 h induce YS losses of about 40% and 71% and UTS losses of 39% and 59%, respectively. The synergistic effect of the stress and the H-charging process leads to a higher loss, 91%, and a faster brittle fracture even though hydrogen content is similar to those firstly H-charged and then tested in air. 相似文献
67.
Yu Tan Yike Wei Kexin Liang Luyao Wang Shenghan Zhang 《International Journal of Hydrogen Energy》2021,46(52):26340-26346
Hydrogen is regarded as a clean and highly efficient renewable energy. The platinum catalytic electrode is widely used in hydrogen evolution reaction (HER), but it has affected its commercial application because of its high cost. Therefore, the study on cost-effective and high-active catalysts toward HER is required to realise large-scale hydrogen production. In this work, we present a novel Pt/NPSSF catalyst prepared by a one-step in-situ deposition of Pt precursor on a nano-porous stainless-steel film (NPSSF) substrate. The prepared catalyst was evaluated in acidic and alkaline conditions for its HER activities. The preliminary results demonstrate that the Pt/NPSSF electrodes have superior catalytic activity for HER. The hydrogen overpotential of Pt/NPSSF is ?70mV (RHE) in the alkaline solution, which is lower than the Pt electrode of ?184mV. At the same time, we also obtained ?71.2 mV of overpotential for the Pt/NPSSF electrode, which is similar to the ?73mV of Pt electrode in the acid solution. The Tafel graphs plotted from the LSV curves indicate the different HER mechanism in the alkaline and acid solution. The HER kinetics of the Pt/NPSSF were studied using EIS. Comparing Pt/NPSSF to Pt electrode, the multi-pore structures of NPSSF and the Pt nanoparticles active sites decrease the charge transfer-resistance for the HER process. The facile preparation, high efficiency and low value of the Pt/NPSSF composite electrodes demonstrate the promising applications in HER. 相似文献
68.
摘要:基于热酸洗腐蚀原理与图像光学理论,提出运用金属低倍组织灰度分析技术(灰度分析法)获取中高碳钢铸坯的低倍组织中不同位置不同区域不同尺度的一维、二维C元素含量分布。偏析严重的位置得到的C元素含量高,初始凝固的晶粒中心位置得到的C元素含量低,说明通过灰度分析法计算的C元素含量分布能与低倍组织形貌很好地对应。同时,通过电子探针与灰度分析法的测量结果对比,发现二者C元素含量的变化趋势具有很好的一致性,这验证了灰度分析法的有效性。另外,低倍组织图像整体亮度的改变不会造成由灰度分析法所测量的C元素含量发生明显改变,则表明灰度分析法对测量环境的变化具有一定的抗干扰能力,也间接说明了其可靠性。 相似文献
69.
70.
摘要:为了探究不同镁含量对非调质钢中组织和硫化物形态、尺寸、分布及成分的影响,采用蔡司金相显微镜、扫描电子显微镜、小样电解等方法,分析了经高温电阻炉冶炼不同镁添加量的49MnVS3非调质钢。结果表明,由于镁蒸气压较高,在实验室冶炼中大量挥发,导致钢中镁的实际平均收得率仅为310%;镁的质量分数为0~22×10-6时,随着镁的质量分数的增加,钢中硫化物形态由Ⅱ类逐渐向Ⅰ类、Ⅲ类转变;钢中硫化物尺寸增大,硫化物的分布均匀性得到显著改善;钢中复合夹杂物比例明显增加,但MnS的比例出现下降;形成了细小弥散的氧化物,增加了奥氏体形核质点,具有细化组织的趋势。 相似文献